Abstract
Several new 2-boron substituted dienes have been prepared and characterized. Their reactivity in Diels-Alder reactions has been examined and the boron substituted cycloadducts of those cycloaddition reactions have been used in cross coupling reactions. One-pot tandem Diels-Alder/cross coupling reactions of 2-boron substituted dienes are then also reported along with some experimental evidence that these one-pot reactions are proceeding through a Pd(II)-catalyzed Diels-Alder/cross coupling reaction pathway.
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