Preparation and characterization of modified starch‐based plastic film reinforced with short pulp fiber. I. Structural properties

Abstract

AbstractNative corn starch‐ and hydroxypropylated starch (HPS‐) based plastic films were prepared using the short pulp fiber as the reinforcement and the glycerol as the plasticizer. Starch (or HPS) films showed different X‐ray diffraction patterns with the A‐type of native corn starch powder. The crystallinity of films increased with pulp content, but decreased with glycerol content and degree of substitution by hydroxypropylation. Also, the intensity of peaks at 2θ = 15.3 and 17.3° decreased with glycerol content and degree of substitution. The water uptake of films as a function of the relative humidity decreased with pulp content and degree of substitution by hydroxypropylation, but increased with glycerol content. Differential scanning calorimetry (DSC) thermograms showed that the glass transition temperature of films decreased and the endothermic peaks at the melting temperature broadened due to the plasticizing effect and the decrease of the crystallinity, which were caused by the addition of glycerol and the hydroxypropylation. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2100–2107, 2003