Preparation and characterization of graphene derived from low-temperature and pressure promoted thermal reduction

Abstract

Abstract The reduction of graphene oxide was promoted remarkably under pressure via low temperature thermal treatment. Traditionally, graphene oxide is usually reduced in a preheated high temperature environment as a precondition of the thermal reduction. We report a pressure promoted method for low temperature thermal reduction and exfoliation of graphene oxide in large quantity at 260 °C. The physicochemical properties of parent graphite, as well as the microstructure and physicochemical properties of graphene oxide and resultant graphene were investigated by Raman spectrometer, thermograviment analyzer (TGA), transmission electron microscope (TEM), X-ray diffractometer (XRD) and Fourier transform infrared spectroscopy (FT-IR). Results show that graphene oxide was reduced to graphene with less stack via low-temperature pressure promoted thermal treatment, meanwhile, the degree of disorder reduced: the ratio of ID/IG in Raman spectrum decreases from 0.64 to 0.56. Moreover, graphene derived from low-temperature pressure promoted treatment exhibit better thermal stability than graphene oxide, and oxygen functional groups were removed with a high level. All of results exhibit improved comprehensive properties than graphene synthesized via traditional thermal reduction at 1000 °C.