Preparation and characterization of a novel microporous PE membrane supporting composite gel polymer electrolyte

Abstract

A new type of composite gel polymer electrolyte(CGPE) with a blend of polyethylene glycol 200 maleate, methyl methacrylate(MMA) and poly(methyl methacrylate)(PMMA) coated and polymerized on the microporous polyolefin membrane was prepared by means of ultra-violet crosslinking and then soaked in a lithium salt solution. The chemical construction, morphology, ionic conductivity of composite gel polymer electrolytes, and their interfacial stability between lithium metal electrode were characterized by using infrared spectroscopy, 1H NMR measurement, scanning electron microscopy, alternating current impedance and linear sweep voltammetry, respectively. The ionic conductivity of the CGPE reaches 10 − 3 S/cm at room temperature and its electrochemical stability window is 4.7 V, which makes it a potential candidate for application as polymer electrolyte in devices.