Preparation and Adsorption Properties of Soybean Dreg/Hydrocalumite Composites.

Abstract

The application of biomass-based composites in the field of adsorption has attracted extensive attention. Herein, soybean dreg/hydrocalumite composites were prepared by in situ self-assembly from soybean dregs and applied to the adsorption of Congo Red (CR). The composites were characterized by scanning electron microscopy, X-ray diffraction, Fourier infrared spectroscopy, and N2 physical adsorption–desorption. The results showed that the adsorption property of soybean dregs/hydrocalumite for CR was better than that of soybean dregs or hydrocalumite. Effects of preparation and adsorption conditions on the adsorption of CR by soybean dregs/hydrocalumite were also investigated. The removal rate of soybean dregs/hydrocalumite (30%BD-LDH) prepared under the optimized conditions reached 97.4% with a 486.8 mg·g–1 adsorption capacity. Also, the adsorption capacity of 30%BD-LDH was about 2.4 times and 3.0 times that of hydrocalumite and soybean dregs, respectively. In addition, the adsorption process of CR by 30%BD-LDH was more in line with the pseudo-second-order kinetic and Langmuir isothermal models.