Abstract
Titanium is not fully immune to the microbiologically-influenced corrosion, yet highly susceptible to biofouling. Biocorrosion inhibition effect of Ti-5Cu alloy against Pseudomonas aeruginosa was studied using antibacterial test, various electrochemical techniques and surface analysis. Ti-5Cu alloy was verified to effectively reduce the MIC rate. After 14 days of incubation in P. aeruginosa, the icorr of cp-Ti (89.20 ± 12nA cm−2) was significantly greater than that of Ti-5Cu alloy (35.42 ± 5.3nA cm−2). Release of Cu2+ ions which was confirmed by shake-up feature controlled respiration of P. aeruginosa, resulting in strong pitting resistance ability. The outermost layer of Ti-5Cu alloy was predominantly composed of TiO2, but a spot of Ti° was also detected. In contrast, the content of Ti2O3 at sputtering thickness of 0, 2, and 6 nm was higher on the surface of cp-Ti compared with Ti-5Cu alloy. Ti2Cu intermetallic compounds promoted the rapid self-healing property of passive film in the presence of P. aeruginosa.
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