Preliminary assessment of the potential for rapid combustion of pure ammonia in engine cylinders using the multiple spark ignition strategy

Abstract

In pursuit of carbon neutrality, the adoption of zero-carbon fuels in internal combustion engines offers a path to zero carbon emissions. Among such fuels, ammonia (NH3) stands out as an effective hydrogen energy carrier with a higher energy density and a more advanced production-storage-transportation lifecycle than hydrogen (H2) fuel, making it a superior alternative. Nevertheless, achieving high combustion efficiencies in engine cylinders requires the use of fuels with fast flame speeds, since the time scales of the combustion event are practically milliseconds. The inherent flame speed of NH3 falls short, typically necessitating augmentation with H2. Yet, the in-situ generation of H2 from NH3 remains constrained, rendering the flame speed of NH3 less competitive against traditional fuels like gasoline and natural gas. To address the dual challenges of slow flame speed of NH3 and the difficulty of generating large amounts of H2 from NH3 onboard, this study evaluates an alternative method of accelerating the ammonia combustion in the engine combustion chamber through the use of multiple spark plugs, which is limited discussed in existing research. Numerical simulations performed in this study show that the application of the multi-spark strategy increases the mass burn rate, advances the combustion phasing, shortens the combustion duration, increases the engine power output, improves the fuel economy, and reduces the unburned ammonia emissions, all of which indicate that rapid combustion of pure ammonia is achieved in the combustion chamber. Moreover, the use of multiple spark points does not lead to a marked increase in nitrogen oxides emissions, thereby ensuring no added stress on exhaust aftertreatment systems. In addition, pure ammonia combustion appears to be very well adapted to this strategy, as evidenced by the avoidance of excessive cylinder pressures and pressure rise rates—a challenge faced by conventional spark ignition engines, given ammonia notably slower flame speed relative to conventional petroleum-based fuels. Overall, all these findings strongly support that the multi-spark ignition system presents a compelling direction for future zero-carbon ammonia engines. However, it is crucial to address design challenges to ensure that the engine head layout provides sufficient cooling, structural robustness, optimal breathing efficiency, and reliable multi-ignition events within the confined space.