Abstract
The retention values (capacity factors or retention indices) of the isomers of chlorobenzenes with two to six chlorine atoms were predicted by using structure–retention correlations and the calculated contributions of the ortho, meta and para positions of the substituent atoms on the aromatic ring. The method permits the prediction of the retention of every isomer by starting from the measured retention of a few compounds, and does not require the use of all of the possible isomers as standard samples for the identification in complex mixtures.
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