Prediction of long‐term service performance of polymeric materials from short‐term tests: Creep and prediction of the stress shift factor of a longitudinal polymer liquid crystal

Abstract

AbstractThe material studied is a longitudinal polymer liquid crystal (PLC). The creep behavior of the PLC is examined in the region of nonlinear viscoelasticity. The creep compliance D curves at nine different stress σ levels, from 10 to 50 J.cm−3 at a constant temperature are determined and shifted along the log time axis for σref = 10 J · cm−3 to produce the D versus t/aσ master curve. A fairly general formula for stress shift factor aσ based on free volume vf and the chain relaxation capability (CRC) derived by one of the authors is applied. The formula predicts values that agree with the experimental ones within the limits of the experimental accuracy. Thus, experiments at several stress levels can serve for prediction of long‐term behavior from short‐term tests. The same value of the Doolittle constant B is obtained separately from temperature shift and stress shift experiments for the PLC.