Abstract
AbstractThe fundamental methods for the prediction of segregation enthalpy and entropy of any element at any grain boundary are outlined, based on grain boundary segregation diagrams and a linear dependence between segregation entropy and enthalpy. The capability of these methods is evaluated by comparison of the predicted interfacial composition of α‐iron‐based binary systems with Si, Al, P, Sn, S, Sb, Ni, Mo, C and B with recently measured experimental data for the same systems. Copyright © 2002 John Wiley & Sons, Ltd.
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