Pozzolanic behaviour of compound-activated red mud-coal gangue mixture

Abstract

The pozzolanic behaviour of compound-activated red mud-coal gangue has been investigated through TG, DTA, XRD, FTIR and 27Al MAS NMR. From viewpoint of reaction kinetics, it is found that the pozzolanic reaction mechanism of the compound-activated red mud-coal gangue — lime system is clearly consistent with diffusion control up to 14 days, and the reaction rate constant calculated from Jander equation decreases with the increase of CaO addition in the system. The hydration products formed in the red mud-coal gangue — lime systems at ambient temperature are essentially aluminous C–S–H and Ca 3Al 2O 6.xH 2O. From TG analysis results, it is thought that the high amount of Ca(OH) 2 in the pastes of studied system is not conducive to the continual increase of non-evaporable water content of the hydration products. Of particular interest, 27Al MAS NMR proved to be an effective technique to obtain valuable information of Al [4] in C–S–H and Al [6] in Ca 3Al 2O 6.xH 2O.