Abstract

In this work, the novel phthalonitrile derivatives and their peripheral/nonperipheral phthalocyanine analogues including 7-oxy-3-(p-thiomethylphenyl) coumarin were synthesized and purified. All these novel compounds were characterized by common characterization methods such as FT-IR, UV–vis, MALDI-TOF, 1H-NMR and elemental analysis. Furthermore, the photochemical and photophysical properties of newly synthesized zinc(II) and indium(III) phthalocyanines were investigated in N,N-dimethylformamide (DMF) solutions. The substituent effect toward the phthalocyanine center and the metal effect on the photophysicochemical properties were also investigated.

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