Potential of crude xylano-pectinolytic enzymes in bleaching of rice straw pulp for improving paper quality and reducing toxic effluent load generation.

Abstract

The objective of this study was to check the potential of crude xylano-pectinolytic enzymes in bleaching of rice straw pulp, in order to reduce the toxic waste load for managing the environmental pollution. The xylano-pectinolytic enzymatic bleaching step for delignification was found to be most effective at pulp consistency 1:10 g/ml, xylanase:pectinase dose of 9:4 IU/ml, pH 8.5 and treatment time 180 min at temperature of 55 °C, and resulted in lowering of kappa number of the rice straw pulp by 15.29%. In subsequent bleaching stages, this enzymatic pre-bleaching treatment also resulted in 30% reduction of active chlorine dioxide dose without any loss of optical properties. Significant improvement in various physical properties of the enzymes treated pulp, tear index (15.43%), breaking length (11.11%), double fold number (25.92%), burst index (9.88%) and viscosity (13.63%), and Gurley porosity (39.86%) was also noticed. This approach resulted in reduction of BOD and COD values by 21.07% and 26.57%, respectively. This is the first study on the use of crude xylano-pectinolytic enzymes for bio-bleaching of rice straw pulp.