Abstract

This study aims to create oleogels by combining beeswax (BW) and plant sterols with diacylglycerol corn oil (DGCO). The findings demonstrate that gel formation occurred with 6:4 (w/w) blends of BW with sitosterol (Sit) and β-sitosterol (PS) oils at a 20% (w/w) concentration, while BW-plant sterol ester (PE) gelled at a 15% (w/w). Texture analysis reveals that the maximum hardness of the BW-PE oleogel (582.62 N) was approximately five times higher than other oleogels and DGCO-based oleogel displayed greater hardness (52.39 N∼140.89 N) and lower viscosity (−57.06 N∼−25.94 N). The melting point of the DGCO-based oleogel increased from 48.35 °C to 57.64 °C as the BW content increased and microstructure from polarized light microscope displayed that he BW-PE oleogel presented itself as bundle-shaped crystals and with an augmentation in concentration, the dimensions of these crystals diminished while their abundance escalated. Notably, the BW-PE oleogel based on DGCO exhibited the most condensed structure. X-ray diffraction analysis revealed oleogel based on DGCO corresponding to characteristic peaks of β′and β-type crystals while the infrared spectroscopy demonstrated no new peaks formation whether for hydrogen bonds or covalent interactions in DGCO-based oleogel. These stable physical DGCO-based gel system provide a choice for the preparation of functional oleogels with lipid-lowering ingredients.

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