Abstract

Positron-annihilation lifetime and Doppler broadening energy spectra have been measured in high-temperature superconductors $\mathrm{Y}{\mathrm{Ba}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{6+\ensuremath{\delta}}$ as a function of temperature between 10 and 293 K. The observed positron lifetime and Doppler boradening $S$ parameter show an onset increase near the superconducting critical temperature (${T}_{c}=90$ K). This variation does not exist in a similar nonsuperconducting sample that contains a saturated oxygen vacancy content. These results give evidence that the oxygen vacancy and electronic structure change play an important role for high-${T}_{c}$ superconductivity.

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