Portable stirring device for the on-site extraction of environmental waters using magnetic hydrophilic-lipophilic balance tape

Abstract

The spatial heterogeneity of environmental systems makes sampling at multiple locations crucial to provide complete and representative information. The on-site application of an extraction technique simplifies the sampling logistics, increasing sample integrity during transportation and storage. This article presents a portable, simple, and low-cost device capable of performing the simultaneous on-site extraction of several environmental water samples. The device consists of a small electric motor integrated into the plastic cap of a conventional glass bottle and operated with a portable battery. The electric motor provides stirring to a novel magnetic sorptive phase based on the deposition of hydrophilic-lipophilic balance (HLB) particles over a magnetic tape. The use of open technology makes the device globally affordable. In this first approach, the isolation and preconcentration of atrazine and simazine have been selected as proof of concept. Using an internal standard made unnecessary the adjustment of the ionic strength before the extraction, thus simplifying the analytical procedure. Under the optimum conditions and using direct infusion mass spectrometry as the instrumental technique, detection limits as low as 15 ng/L were obtained. The precision calculated at three different levels was better than 8.3%. The accuracy, calculated with spiked samples, indicates the applicability of the approach for environmental water analysis.