Abstract
AbstractCatalytic direct functionalization of unreactive CH bonds represents a sustainable and more atom economical transformation process. Porphyrin and phthalocyanine derivatives show promising catalytic activities in direct CH arylation reactions. These reactions share a common CC bond formation process via homolytic radical substitution. This review summarizes the catalytic direct CH arylation reactions catalyzed by metalloporphyrins, free base porphyrins and free base phthalocyanines.
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