Abstract

Lanthanide metal–organic frameworks (Ln-MOFs) have attracted increasing attention as an emerging type of porous materials in the last decades due to their high porosities, adjustable pore sizes/sharps, ready functionalization, as well as high thermal/chemical stability. In this chapter, we seek to not only provide a comprehensive review focusing on porous Ln-MOF materials for a wide range of applications in gas storage and separation, such as H2 storage, selective CO2 capture and separation, and H2 and CH4 purification, but also highlight some strategies as a means of effectively enhancing their gas storage capacities and selectivities.

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