Abstract

Employing advanced electrochromic technology, the low energy-consuming smart windows seamlessly regulate light transmission, optimizing energy efficiency without compromising comfort. This innovation marks a significant stride toward sustainable architecture, offering dynamic control over interior luminosity while reducing reliance on conventional power sources. In that context, a porous perylene diimide (PDI) and triazine-containing covalent polymeric framework, PD-CPF, was synthesized for electrochromic (EC) applications. The PD-CPF-based electrochromic device (ECD) exhibited a multicolored, durable visible-to-NIR electrochromism when used in an ECD. The low-power-consuming (3.05 mW/cm2) electrochromic (EC) smart window remarkably lowered the solar irradiance gain by 68%.

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