Abstract
AbstractThe 2D porous copper(I) complex with 1,3‐dicyanobenzene (DCB), [Cu(DCB)2](PF6)(Me2CO) 1, exhibits channels along axis c, in which one molecule acetone and one anion PF−6 per formula unit are included respectively. The reversible incorporation of guest acetone and acetonitrile, as well as the anion exchange from PF−6 to BF−4 or CF3SO−3, was investigated by thermogravimetric (TG) analysis, 1H NMR spectra and/or infrared absorption spectroscopy. Additionally, the incorporation of benzene and toluene into complex 1 was also discussed. Complex 1 exhibited size selectivity for guest inclusion or anion exchange.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
