Abstract
By rational assembly of polytorsional-amide [N,N′-bis(4-methylenepyridin-4-yl)-1,4-naphthalene dicarboxamide (L)] and polytorsional-carboxylates [H2ADI = adipic acid, H2PIM = pimelic acid, H2SUB = suberic acid], three new Cd-based coordination polymers (CPs) C30H30CdN4O7 (1), C31H32CdN4O7 (2) and C31.03H30.55CdCl0.24N4O5.52 (3) were successfully synthesized. CPs 1–2 and 3 are 2D networks and a 3D framework, which all display 3,5-connected topologies with different structural details. The effects of carboxylates with different carbon chains on the structure of the complexes were studied. Fluorescence experiments show that CPs 1–3 have good multi-functional sensing ability for metal cations (Fe3+), anions (MnO4−, CrO42−, Cr2O72−) and organochlorine pesticides (2,6-dichloro-4-nitroamine) with good anti-interference and recyclable characteristics. The possible sensing mechanism is also investigated in detail.
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