Abstract
The T-x diagram of the polythermal section Sn4P3-Sn4As3 of the Sn-P-As system was constructed using the results of X-ray powder diffraction and differential thermal analyses. A continuous series of solid solutions (Sn4P3) x (Sn4As3)1 − x was found to exist. The section is not quasi-binary; in a Sn4As3-rich region, this section intersects the peritectic part of the three-phase volume (L + SnAs + α) of the ternary diagram.
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