Polystyrene: A Self-Dispersing, Ultralow Loading Additive for Improving the Breakdown Strength of Polypropylene for High Voltage Power Cable Applications

Abstract

Voltage stabilizers (VSs) with benzene derivatives have received great interest as high-performance additives for improving the electrical durability of polypropylene (PP)-based insulation materials for high voltage (HV) power cable applications. In this work, atactic polystyrene (aPS) was first used as a thermoplastic VS (TVS) to efficiently dope the benzene units into isotactic PP (iPP). The aPS TVS was incorporated in the iPP matrix through melt-mixing, and the domain size of immiscible aPS decreased with the decrease of aPS content. The smaller amount of aPS doping increased the direct current (DC) breakdown strength (BDS) of iPP, even at ultralow loading levels below 0.01 phr. The enhancement ratio of the BDS value of iPP with 0.001 phr of aPS was higher compared to the results obtained for other types of additives reported in the previous literature.