Abstract

The radical of methacrylic acid in water in the presence of matrices i.e., poly-N-vinylpyrrolidone of different MM, polyethylene glycol monolaurate and their mixtures is studied. Under some conditions the transition of the polymethacrylic acid molecules during growth from the strong, but short poly-N-vinylpyrrolidone matrix onto the weaker matrix, i.e. polyethylene glycol monolaurate micelles, is shown to be possible. As a result of this substitution reaction both matrices control the growth of the “daughter” chains.

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