Abstract

Abstract Thin fluoropolymer films deposited in an r.f. discharge fed with C 2 F 6 H 2 mixtures were studied. The effect of the electrical characteristics, the substrate temperature and the feed composition on both the chemical structure of the film and on the growth mechanism were analysed. It was found, in particular, that the structure of the film is affected by the H 2 concentration in the feed and by the discharge voltage and current values and that the polymerization rate decreases with temperature after a threshold.

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