Polymer brush-grafted cotton fiber for the efficient removal of aromatic halogenated disinfection by-products in drinking water

Abstract

Apart from the activated carbon, other functional adsorbents are usually not frequently reported for the removal of disinfection by-products (DBPs) in drinking water. In this study, a novel polymer brush-grafted cotton fiber was prepared and for the first time used as adsorbents for the efficient removal of aromatic halogenated DBPs in drinking water in the column adsorption mode. Poly (glycidyl methacrylate) (PGMA) was grafted onto the surface of cotton fibers via UV irradiation, and then diethylenetriamine was immobilized on the PGMA polymer brush through amination reaction to obtain the aminated cotton fibers (ACFs). The adsorption performance of the prepared ACF was investigated with eight aromatic halogenated DBPs via dynamic adsorption experiments. The results revealed that ACF showed significantly longer breakthrough point (38,500–225,500 BV) for aromatic halogenated DBPs compared with the granular activated carbon (150–500 BV). Thomas model was used to fit the breakthrough curves, and the theoretical value of the maximum adsorption capacity ranged from 14.76 to 89.47 mg/g. The enhanced adsorption performance of the ACF for aromatic halogenated DBPs was mainly due to the formation of hydrogen bonds. Additionally, the partially protonated amine groups also improved the adsorption performance. Furthermore, the ACF also showed remarkable stability and reusability.