Polyethylene Composite Particles as Novel Water Plugging Agent for High-Temperature and High-Salinity Reservoirs

Abstract

Water channeling has always been one of the urgent problems during oilfield development. Especially for fractured reservoirs with high temperature, high salinity, and severe heterogeneity (e.g., deep carbonate reservoirs), it is difficult for the existing plugging agents to realize effective water plugging. In this paper, chemically stable polyethylene (PE) was selected as the main component to prepare multiscale PE composite particles that can be easily dispersed in water as a novel water plugging agent for fractured reservoir with high temperature and high salinity. The characteristics of the prepared PE composite particles, including thermal stability, salinity resistance, dispersibility, coalescence properties, and microscopic morphology, were systematically studied. Finally, the plugging performance of the particles was evaluated through visual physical simulation experiments. The prepared PE composite particles can be pulverized to a minimum of 6 μm, and the particle size is controllable within 6 μm to 3 mm by adjusting the pulverization parameters. The PE composite particles are easily dispersed in water by adding the dispersant, which is conducive to injectivity during the field application process. The particle size remains unchanged under the condition of salinity of 0–3.0 × 105 mg/L, which indicates that the prepared particles have good salt-resistant stability. After high-temperature aging, the particles adhere to each other, and the size of the agglomerations reach a size dozens of times larger than the initial size of the particle, which is conducive to effective plugging in fractures. Thermal degradation behavior analysis shows that the PE composite particles could theoretically withstand a temperature of 434.4 °C. It can be seen from the SEM images that after high-temperature melting and kneading with other components, the microstructure changes from a fibrous structure to a dense flake structure. Physical simulation experiments show that the PE composite particles accumulate in fracture after injection and form effective plugging through coalescence and adhesion of the particles, thereby realizing water flow diversion.