Abstract

Conventional polymer flooding include polymer flooding, surfactant-polymer flooding (SP), alkaline-surfactant-polymer flooding (ASP), and crosslinked polymer gel flooding. However, these technologies in oilfield, especially in high temperature and high salinity, are limited due to the poor ability of temperature and salinity resistance of polymer. In this work, a novel polymer particle (soft microgel, SMG) is used as the research object under the reservoir condition of high salinity (20 × 104 mg/L) to evaluate the physical and chemical properties of submillimeter-scale SMG and the effect of profile control and oil displacement. The investigation of the physical and chemical properties of submillimeter-scale SMG shows that it has the characteristics of low viscosity, easy injection, good plugging property, swelling property, rheological property, and excellent thermal stability. After 6 months of high temperature and high salinity aging, there is no hydration and hydrolysis of submillimeter-scale SMG as the traditional polymers under high temperature and high salinity. The parallel two-core flooding experiments indicate that the submillimeter-scale SMG has a better effect of profile control and oil displacement, which increases the fraction flow rate( f w ) of low-permeability core from 5.12% before SMG-flooding to 85.29% and the total increase of recovery as high as 14.07%. The comprehensive analysis demonstrates that the submillimeter-scale SMG has the potential to solve the problem that the polymer flooding cannot be applied to the high temperature and high salinity reservoir, and it is also expected to improve the uneven waterflooding in the reservoir.

Highlights

  • Conventional and mature EOR technologies based primarily on polymer (HPAM) include polymer flooding, surfactantpolymer flooding (SP), alkaline-surfactant-polymer flooding (ASP), and crosslinked polymer gel flooding. ese technologies have achieved significant success worldwide [1,2,3,4,5,6,7,8,9]

  • Many researchers have carried out a lot of studies aiming at these problems, such as the development of thermo-resistant and salt-resistant monomer copolymer, comb polyacrylamide polymer, and hydrophobic association polymer. e temperature resistance and salinity resistance of these polymers have been improved to some extent, but these problems have not been solved fundamentally. erefore, the application of polymer flooding is limited in high temperature and high salinity oilfield

  • Given the problems for traditional polymer, Wu et al proposed the theory of targeting oil displacement by water dispersion system, established the waterflooding sweep control technology, and developed the corresponding novel Journal of Chemistry particle polymer dispersion system [10,11,12, 16, 17]

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Summary

Introduction

Conventional and mature EOR technologies based primarily on polymer (HPAM) include polymer flooding, surfactantpolymer flooding (SP), alkaline-surfactant-polymer flooding (ASP), and crosslinked polymer gel flooding. ese technologies have achieved significant success worldwide [1,2,3,4,5,6,7,8,9]. SMG can be prepared from acrylamide, 2acrylamide-2-methylpropylsulfonic acid, and self-made polymerizable temperature-resistant monomer by reversedphase microemulsion polymerization, reversed-phase emulsion polymerization, and reversed-phase suspension polymerization. It can be divided into nanoscale SMG, microscale SMG, and submillimeter-scale SMG. In order to address this application challenge, in this work, a novel particle polymer (soft microgel, SMG) was used as the research object to evaluate the physical and chemical properties of submillimeter-scale SMG and the effect of profile control and oil displacement under high temperature and high salinity. Rough these investigations, we strive to provide more meaningful guidance for submillimeter-scale SMG performance optimization and improve the application of polymer flooding in oilfield with high temperature and high salinity

Materials and Methods
Results and Discussion
Conclusions
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