Polycyclic aromatic hydrocarbons in sedimentary cores of Tibetan Plateau: Influence of global warming on cold trapping.

Abstract

Cold condensation is an important pathway for polycyclic aromatic hydrocarbons (PAHs) depositing at remote alpine lakes after long-range atmospheric transportation. However, in the context of global warming, the obvious temperature rise in the Tibetan Plateau (TP) might have an impact on the air deposition of PAHs by controlling the extent of cold condensation. To investigate the influence of rising temperatures on the atmospheric deposition of PAHs, two dated sedimentary cores from Pumoyum Co Lake (PC) and Selin Co Lake (SC) were collected, respectively and concentrations of 16 individual PAHs were measured. In both PC and SC, the total concentration of 16 PAHs presented relatively lower levels in four historical periods of "hot anomaly" including 1973-1975, 1988-1989, 1998-1999, and 2006-2007. This indicated that the hot temperatures might restrict the atmospheric deposition of PAHs. Besides, the results of the principal component analysis did discriminate those "hot anomalies". As the temperature kept increasing in TP, for low molecular weight PAHs and high molecular weight PAHs, the influence of rising temperatures on the cold condensation was different. Therefore, it was identified that the effect of global warming on the environmental fate of POPs cannot be neglected, especially in alpine regions like TP.