Abstract

In the title complex, [Cd(SCN)2(C4H8O2S)2]n, the CdII atom, on an inversion centre, is within a distorted N2S2O2 octa­hedron and the five-membered ring has a distorted envelope conformation. In the crystal structure, neighbouring Cd atoms are connected by –SCN– bridges, leading to the formation of an infinite three-dimensional –Cd–NCS–Cd– network.

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