Abstract
In the title compound, [Cu3(C5H3N2O2)2(N3)4]n, one of the CuII atoms lies on an inversion centre and is octahedrally coordinated by two bidentate chelating pyrimidine-2-carboxylate ligands and two azide anions, each of which gives an N:N-bridge to the second inversion-related CuII centre in the formula unit. The second CuII atom is five-coordinated with a distorted square-pyramidal coordination sphere comprising a single bidentate chelating pyrimidine-2-carboxylate anion and three azide N anions, two of which doubly bridge centrosymmetric CuII centres, giving a two-dimensional network structure extending parallel to (010).
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