Poly[bis(trimethylammonium) [hexa-μ-cyanido-cadmium(II)dicopper(I)

Abstract

The title compound, {(C3H10N)2[CdCu2(CN)6]}n, has been synthesized as an alternative to the high-emitting complexes containing more expensive metals. The CN−ligands make linkages between the CuIand CdIIions to form the coordination polymer, [CdCu2(CN)6]n2−, which is a three-dimensional framework classified as pyrite net (pyr). The net has a void space for accommodating a trimethylammonium ion located on a threefold rotation axis. The CdIIion lies on a special position with site symmetry -3 and is octahedrally coordinated by six N atoms. The CuIion is located on a threefold rotation axis and has a trigonal-planar coordination geometry formed by three C atoms. In the three-dimensional net, two CuIions are arranged closely [Cu...Cu = 3.9095 (5) Å], but the distance is not short enough to suggest a CuI–CuIinteraction. The crystal studied was a merohedral twin (twin operation 2[101]), the refined component ratio being 0.9202 (7):0.0798 (7). A powder of the title compound shows strong luminescence with an emission maximum at 509 nm and a quantum yield of 98% at room temperature.