Abstract
The title compound, [Ag(AsC18H15)4]PF6, crystallizes with the cation on a threefold rotation axis and the anions on positions with site symmetry \overline3. The Ag atom is surrounded by four arsine ligands forming a distorted tetrahedral configuration. The Ag—As distances are 2.6381 (6) and 2.6499 (9) Å, and the As—Ag—As angles are 108.91 (1) and 110.03 (1)°.
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