Abstract

The authors report on poly(9,9-dioctylfluorene) (PFO)-based light-emitting diodes exhibiting an emission spectrum which was previously attributed to the so-called β phase. These devices were prepared by drop cast from dilute toluene solutions. Photoluminescence and electroluminescence spectra, recorded at room temperature, show no evidence of the usual amorphous phase emission. Devices with pure β-phase emission exhibit a higher color stability, upon increase of the driving voltage, than those based on amorphous PFO.

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