Abstract
The title compound, [Co(C5H4NPO3)]n, is a three-dimensional network coordination polymer containing tetrahedrally coordinated CoII bound to one N atom from one 3-pyridylphosphonate ligand and three O atoms, each from three other distinct 3-pyridylphosphonate ligands. The structure exhibits two-dimensional cobalt phosphonate layers, parallel to the ac crystal plane, constructed from the junction of Co3O6P3 12-membered rings. The inorganic layers are pillared through the N-atom donors of the tethering pyridyl rings to produce the three-dimensional crystal structure of (I).
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