Abstract

Abstract Poly(3,4-ethylenedioxythiophene) (PEDOT) grains were synthesized by solvent-free chemical oxidative polymerization in one-step and one-pot manner. The resulting PEDOT grains had atypical shapes with a volume-average diameter of 57 ± 45 µm and showed an electrical conductivity of 1.9 × 10−3 S cm−1. Furthermore, it was clarified that the PEDOT grains showed light-to-heat photothermal property.

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