Abstract
In the title complex, [Cu2Br2(C14H11N5)]n, there are two crystallographically independent CuI cations with different coordination geometries: one has tetrahedral geometry (CuBr2N2), and the other adopts a trigonal geometry (CuBr2N). The 2-amino-4-(2-pyridyl)-6-(4-pyridyl)pyrimidine (appm) ligand acts as a bridging ligand. Four Br− anions connect four CuI cations to form an eight-membered ring, and the appm ligands link adjacent eight-membered rings to construct a one-dimensional ribbon chain.
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