Abstract
In the title dinuclear complex, [Cu2(C14H20ClN4O)ClO]·3H2O, one CuII cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both CuII cations are N,N′,O-chelated by one arm of the 2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolate anion, and one oxide anion bridges the two CuII cations, forming a dinuclear complex. One of the CuII cations is further coordinated by an Cl− anion in the apical direction. In the crystal, lattice water molecules are linked with the complex molecule via O—H⋯Cl hydrogen bonds while O—H⋯O hydrogen bonding occurs between lattice water molecules , forming three-dimensional network structure.
Highlights
In the title dinuclear complex, [Cu2(C14H20ClN4O)ClO]Á3H2O, one CuII cation assumes a distorted square-planar coordination geometry and the other a distorted squarepyramidal coordination geometry
One of the CuII cations is further coordinated by an ClÀ anion in the apical direction
Lattice water molecules are linked with the complex molecule via O— HÁ Á ÁCl hydrogen bonds while O—HÁ Á ÁO hydrogen bonding occurs between lattice water molecules, forming threedimensional network structure
Summary
In the title dinuclear complex, [Cu2(C14H20ClN4O)ClO]Á3H2O, one CuII cation assumes a distorted square-planar coordination geometry and the other a distorted squarepyramidal coordination geometry. Both CuII cations are N,N0,O-chelated by one arm of the 2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolate anion, and one oxide anion bridges the two CuII cations, forming a dinuclear complex. One of the CuII cations is further coordinated by an ClÀ anion in the apical direction. Lattice water molecules are linked with the complex molecule via O— HÁ Á ÁCl hydrogen bonds while O—HÁ Á ÁO hydrogen bonding occurs between lattice water molecules , forming threedimensional network structure
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