Poly[[[μ-1,4-bis-(pyridin-4-ylcarbon-yl)piperazine-κ2N:N'][μ-2-(2-carboxyl-atoeth-1-en-1-yl)benzoato-κ2O:O2]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology.

Abstract

The title compound, {[Zn(C10H6O4)(C16H16N4O2]·2.5H2O}n, contains five-coordinate ZnII ions inter-mediate between square-pyramidal and trigonal-bipyramidal coordination environments. The ZnII ions are connected by 2-carb-oxy-cinnamate (cca) ligands and N,N'-bis-(pyridine-4-carboxamido)-piperazine (4-pcap) ligands to construct a non-inter-penetrated, tri-periodic coordination polymer with embedded [Zn2(OCO)2] dimeric units. Treating these as six-connected nodes reveals an overall (41263) pcu topology. One of the 4-pcap piperazinyl rings is disordered equally over two sets of crystallographic positions.