Abstract
We present a simple, analytical model of the interaction-induced polarizability of the homonuclear rare-gas diatoms which contains only one free parameter. Electrostatic and exchange contributions to the pair polarizability are derived under the assumption that the electronic properties of each atom can be simulated by a single effective electron whose average distance from the nucleus is determined by the atomic polarizability. The dipole-induced dipole contribution at short internuclear distances is damped as appropriate for any realistic model. The model permits the reproduction of the available measurements of the interaction-induced, binary depolarized Raman spectra of the rare gases.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.