Abstract
2D materials capable of altering innate optical properties are highly demanded with broad photonic and optoelectronic applications, especially for ultrathin and ultracompact optical devices.We first demonstrated electrostatic doping driven structural phase transition in monolayer molybdenum ditelluride (MoTe2). The reversible structural phase transition between the hexagonal and monoclinic phases is directly controlled by electrostatic gating and verified through non-polar and polarized Raman spectra. An interesting hysteresis behavior has been observed in Raman and Second Harmonic Generation (SHG). And crystal orientation during phase change is found to be conserved, making such transition robust. We also discover out-of-plane 2D ferroelectricity in atomically thin In2Se3 crystal. Through Piezoresponse Force Microscopy (PFM) and SHG, we experimentally found that in-plane lattice asymmetry and out-of-plane polarization is dynamically locked during phase change. Such unique locking mechanism stabilizes the polar order and enables a robust 2D ferroelectricity at ambient conditions with a high transition temperature. The discovery is important to the atomically thin sensors and ultrahigh density nonvolatile memory devices.
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