Physico-chemical Characteristics of Individual Aerosol Particles in Marine Atmosphere on South Hemisphere

Abstract

During the 29th Chinese National Antarctic Research Expedition (CHIANRE), individual particle samples were collected from South China to Antarctic during November 2012 to April 2013. A transmission electron microscopy with energy-dispersive X-ray spectrometry (TEM-EDS) was employed to analyze the morphology, mixing state, composition, and relative abundances of individual aerosol particles. Atmospheric particles were classified into four types:sea salt, mineral, S-rich and C-rich. Sea salt aerosols (SSA) were dominant in the marine particles from South China to Antarctic, and they were further divided into three sub-types:fresh SSA, partially aged SSA, and fully aged SSA. Partially and fully aged SSA accounted for 86% of total SSA number. Interestingly, surface of partially aged SSA and fully aged SSA contained abundant rod-like Na2SO4. Mineral dust particles increased in the coastal areas which were influenced by continental air. In addition, we found that S-rich particles were abundant at two sampling sites (the middle eastern of Indian Ocean and Antarctic inland). The back trajectories of air masses indicated that these S-rich particles were mainly formed via the oxidation of dimethyl sulfide (DMS) emitted from the marine phytoplanktons. Our study suggests that the SSA aging process in the South Hemisphere atmosphere was controlled by the DMS which is different from the SSA aging under the influence of anthropogenic pollutants in the North Hemisphere.