Physical properties of shungite

Abstract

Abstract This paper presents the results of physical parameters such as bulk porosity, true density, optical reflectance, dynamic elastic moduli, X-ray diffractograms and EPR spectra, determined for shungite. All shungite samples studied are considerably denser materials than anthracite — high rank coal with similar carbon content. Bright shungites were porous with the very dense matrix, while the dull shungite is compact, almost non-porous material. Elastic moduli of the dull shungite are generally higher than those of bright shungites and anthracite. All shungites studied (including anthracite) exhibit the directional dependence of elasticity. The maximum reflectance values of bright shungites are higher than those for dull shungite and anthracite. That corresponds with the denser matrix of these samples and suggests the greatest ordering of graphene layers in the case of bright shungites and also suggests some similarity to meta-anthracite from Paleozoic basins. Reflectance anisotropy of shungites studied are generally lower than that of anthracite. Ordering of graphene layers in bright shungite, as a high rank coal variety, is obvious, but lower anisotropy than that of anthracite is a surprise. X-ray studies confirm a high density of bright shungite. Interplanar distances dhkl of the shungite (d002 = 3.48 A) are closer to those of anthracite (d002 = 3.52 A) than to those of graphite (d002 = 3.35 A). All results described here show the differences in molecular structure and degree of graphitisation of carbonaceous matter in bright, semi-bright and dull varieties of shungite. Our data could play a key role in production of materials composed of carbon nanoparticles.