Physical and mechanical investigation for polyionic liquid/poly(vinyl alcohol) blends

Abstract

PurposeThis study aims to polymerize of 1-butyl-3-vinylimidazolium bromide (PIL). PIL was embedded into PVA with a different content ratio by casting method. This research also deals with the effect of adding PIL in different proportions to PVA on the electrical and mechanical properties properties in addition to the morphology of the prepared samples.Design/methodology/approach1-Butyl-3-vinylimidazolium bromide was synthesized through quaternization and free radical polymerization. The resulting polymer was characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis and differential scanning calorimetry. In addition to the morphology of PVA, PVA/PIL was investigated by polarizing microscope. Also, the effect of PIL content on the electrical and mechanical properties was evaluated.FindingsThe findings of this study might lead to new applications for PVA and PILs in electrical and dielectrics. The mechanical results revealed that the tensile strength increased slightly with increasing polyionic liquid (PIL) content and decreased above 10% PIL. While the elongation at break increased significantly with increasing PIL content and begin to decrease above 10% PIL. Also, the electrical property of the poly(vinyl alcohol) (PVA)/PIL blends was improved because of the strong plasticizing effect of PIL. Also, the electrical conductivity of these polymer electrolytes is greatly increased. This indicates that the imidazolium-based PIL has an effective approach that leads to an increase in the conductivity of the polymer. The PILs/PVA design will not only enrich the chemical structure but also will contribute to green manufacturing techniques and a processing methodology that enables green membrane manufacture.Originality/valueThis study contributes to green manufacturing techniques and a processing methodology that enables “green” membrane manufacture.