Abstract

A composite of poly(3,4-ethylendioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and multi-walled carbon nanotubes (MWCNTs) was cyclovoltametrically electropolymerized on a fluorine-doped tin oxide (FTO) substrate and used as a counter electrode for a dye-sensitized solar cell. The PEDOT:PSS–MWCNT composite film was investigated using scanning electron microscopy (SEM), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The CV diagrams showed that the PEDOT:PSS–MWCNT composite film has better electro-catalytic activity for the I−/I3− redox reaction than the conventional platinized FTO. The best energy conversion efficiency was observed in EIS data with an MWCNT content of 0.002 wt %.

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