Abstract
The study of the photophysical properties of self-assembled coordination cages and their host/guest complexes is a rapidly growing and important field. Self-assembly of multiple chromophores—whether metal-based or ligand-based—in a cage provides a way to create a high concentration of chromophores in a specific geometric arrangement that could not be achieved otherwise. Binding of guests in the cage cavities both moderates their own photoreactivity due to confinement effects and also allows them to modulate or interact with cage-based excited states allowing for functions such as sensing behavior and photocatalysis to arise.
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