Photonic Plasticines with Uniform Structural Colors, High Processability, and Self-Healing Properties.

Abstract

Despite the vast variety of colloidal superstructures available in soft matter photonics, it remains challenging to balance the trade-off between their optical microstructures and material processability. By synergizing colloidal photonics and dynamic chemistry, a type of photonic "plasticine" with characteristics of uniform structural colors, high processability, and self-healing is demonstrated. Specifically, a boronate ester bond-based macromonomer is first prepared through complexation between the diols of polyvinyl alcohol and the boronic acid group of 3-(acrylamido) phenylboronic acid in the presence of concentrated silica colloids. Upon photopolymerization, the dynamic photonic plasticine is formed in situ as the result of the crosslinking of the boronate ester bonded networks. The randomly packed colloids inside the plasticine compose the amorphous photonic crystals, giving rise to angle-independent structural colors that would not compromise during subsequent processing steps; the reversible nature of the boronate ester bonds endows the plasticine with self-adaptable and self-healing properties. Further, the plasticine is also compatible with common shaping methods, that is, cutting, molding, and carving, and thus can be facilely processed into 3D structural colored objects, holding great potentials in fields such as bio-encoding, optical filters, anti-counterfeiting, etc.