Photoluminescence processes in τ-phase Ba1.3Ca0.7-x-y SiO4:xDy 3+/yTb3+ phosphors for solid-state lighting.

Abstract

The τ-phase Ba1.3Ca0.7-x-ySiO4:xDy3+/yTb3+ phosphors co-doped with Dy3+ (x = 0.03) and Tb3+ (y = 0.01–0.05) trivalent rare-earth ions were prepared by the gel-combustion method. The structure–property relation of the samples was examined by X-ray diffraction, scanning electron microscopy and spectrophotometer. Here, the effect of Tb3+'s concentration on the spectroscopic properties of Ba1.3Ca0.7-x-ySiO4:xDy3+/yTb3+ phosphors was explored by using the photoluminescence excitation, emission and decay curves. Importantly, the photonic energy transfer from (Dy3+:4F9/2 + Tb3+:7F6) to (Dy3+:6H15/2 + Tb3+:5D4) was observed, in which the Dy3+ ions act as a light-emitting donor whereas the Tb3+ ions as a light-absorbing acceptor, resulting in an enhanced emission from the co-doped Ba1.3Ca0.7-x-ySiO4:xDy3+/yTb3+ (x = 0.03 and y = 0.01–0.05) phosphors. Finally, the chromaticity coordinates were determined from the measured emission spectra, locating at the green and white light regions. This observation indicates that the characteristic emission colour could be tuned from white to green by varying Tb3+ concentrations under ultraviolet light.