Abstract

Abstract The energy distribution of the valence band states of cubic β-HgS was investigated by means of photoemission spectroscopy. The energy positions of the spectral features observed were used to determine band energies at high symmetry points of the Brillouin zone. Changes in the binding energy of Hg 5d states in cubic mercury chalcogenides were analyzed and the role of the interaction between Hg 5d and S 3p states in β-HgS was estimated.

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