Abstract
Cuprous oxide (Cu2O) films are electrodeposited on fluorinated tin oxide (FTO) substrates with controlled crystallographic orientation and optimized film thickness. The Cu2O films exhibit a (100)-to-(111) texture change and a pyramid-to-cuboidal crystallite morphology transformation by increasing the electrodeposition current density. The cuboidal crystallites enclosed by (100) sidewalls and (111) truncated surfaces demonstrate better photoelectrochemical property than the pyramid crystallites. By introducing a copper(I) telluride (Cu2Te) layer in between Cu2O and FTO, the photocurrent density increases 70% for the (111)-textured Cu2O film in a 1 M Na2SO4 solution under AM1.5 G illumination. The enhancement is mainly attributed to the improved separation of photocarriers in the illuminated Cu2O film by pumping hole carriers to the Cu2Te layer. In contrast to typical electron pathway management, this study provides an alternative route to improve the photoelectrochemical performance of Cu2O-based photocathodes through hole pathway modification.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
